WebJul 26, 2024 · Compared with their THF-bound hexacopper(I) monomers and protonated ligands, these ligand-unsupported cuprophilic interactions are shown to be weak by Raman spectroscopy. DFT calculations suggest the ligand-unsupported cuprophilicity originate from weak attractive orbital interactions, and the strength is estimated to be 2.4 kcal mol-1 . WebSep 15, 2024 · A solid AND logic stimuli-responsive material with bright nondestructive performance designed by sensitive cuprophilicity. / Shan, Xiao Chen; Jiang, Fei Long; Zhang, Hua Bin et al. In: Chemical Communications, Vol. 49, No. 87, 08.10.2013, p. 10227-10229. Research output: Contribution to journal › Article › peer-review
What is Complicity or Accomplice Liability? - FindLaw
Web[Cu (SCN)] (1), which can also be viewed as a 3-D network constructed by linkages of 2-D sheets and 1-D chains via unsupported CuI-CuI interactions. The CuI-CuI contact of 2.651 (4) A in 1 is the... WebNov 17, 2000 · DFT calculations suggest the ligand‐unsupported cuprophilicity orginate from weak attractive orbital interactions, and the strength is estimated to be 2.4 kcal/mol. View. Show abstract. rms wells fargo
Metallophilicity versus ?-? Interactions: Ligand-Unsupported ...
WebMay 22, 2024 · Cuprophilicity is still under debate, while aurophilicity and argentophilicity are well recognized. I.-C. Chen, Y.-C. Tsai, and co-workers report in their Communication on page 9925 ff. the synthesis and characterization of two dodecacopper(I) chain-like complexes via intermolecular Cu–Cu coupling of two linear hexacopper monomers. Their … WebJan 10, 2014 · Three 2D luminescent isomeric porous coordination polymers are synthesized and characterized. Their luminescence properties can be modified by grinding and they can act as mechanochromic materials and their properties are probably related to the weak interactions of cuprophilicity and π–π interactions. Supporting Information … WebDec 29, 2004 · To verify whether attractive metallophilic interactions exist in the dimer-of-dimers [Cu2(ophen)2]2(Hophen=1H-[1,10]phenanthrolin-2-one) (1), we designed and … snacks to bring to club meeting