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Cuprophilicity

WebJul 26, 2024 · Compared with their THF-bound hexacopper(I) monomers and protonated ligands, these ligand-unsupported cuprophilic interactions are shown to be weak by Raman spectroscopy. DFT calculations suggest the ligand-unsupported cuprophilicity originate from weak attractive orbital interactions, and the strength is estimated to be 2.4 kcal mol-1 . WebSep 15, 2024 · A solid AND logic stimuli-responsive material with bright nondestructive performance designed by sensitive cuprophilicity. / Shan, Xiao Chen; Jiang, Fei Long; Zhang, Hua Bin et al. In: Chemical Communications, Vol. 49, No. 87, 08.10.2013, p. 10227-10229. Research output: Contribution to journal › Article › peer-review

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Web[Cu (SCN)] (1), which can also be viewed as a 3-D network constructed by linkages of 2-D sheets and 1-D chains via unsupported CuI-CuI interactions. The CuI-CuI contact of 2.651 (4) A in 1 is the... WebNov 17, 2000 · DFT calculations suggest the ligand‐unsupported cuprophilicity orginate from weak attractive orbital interactions, and the strength is estimated to be 2.4 kcal/mol. View. Show abstract. rms wells fargo https://ayscas.net

Metallophilicity versus ?-? Interactions: Ligand-Unsupported ...

WebMay 22, 2024 · Cuprophilicity is still under debate, while aurophilicity and argentophilicity are well recognized. I.-C. Chen, Y.-C. Tsai, and co-workers report in their Communication on page 9925 ff. the synthesis and characterization of two dodecacopper(I) chain-like complexes via intermolecular Cu–Cu coupling of two linear hexacopper monomers. Their … WebJan 10, 2014 · Three 2D luminescent isomeric porous coordination polymers are synthesized and characterized. Their luminescence properties can be modified by grinding and they can act as mechanochromic materials and their properties are probably related to the weak interactions of cuprophilicity and π–π interactions. Supporting Information … WebDec 29, 2004 · To verify whether attractive metallophilic interactions exist in the dimer-of-dimers [Cu2(ophen)2]2(Hophen=1H-[1,10]phenanthrolin-2-one) (1), we designed and … snacks to bring to club meeting

A theoretical study of the ethylene-metal bond in complexes …

Category:Using cuprophilicity as a multi-responsive chromophore …

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Cuprophilicity

Cuprophilicity-Induced Cocrystallization of [Cu 2 (4,4‘-bpy)(CN) 2 ] …

WebThe organic ligand 4-dpda is chosen to amplify the perturbation toward metallophilic interations for steric hindrance, and many of the molecular interactions of its multi- … WebCuprophilicity, a still elusive concept: a theoretical analysis of the ligand-unsupported CuI–CuI interaction in two recently reported complexes - Chemical Communications (RSC Publishing) Jump to main content Jump to site search Publishing Journals Books Databases Advanced Log in / register Issue 11, 1998 Previous Article Next Article

Cuprophilicity

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WebJun 7, 2013 · Request PDF Using cuprophilicity as a multi-responsive chromophore switching color in response to temperature, mechanical force and solvent vapors A … WebDec 29, 2004 · To verify whether attractive metallophilic interactions exist in the dimer-of-dimers [Cu 2 (ophen) 2] 2 (Hophen=1H-[1,10]phenanthrolin-2-one) (1), we designed and synthesized a series of such [M 2 L 2] 2 structures by varying the d 10 metal and/or the ligand (M=Cu I or Ag I, L=ophen or obpy; Hobpy=1H-[2,2′]bipyridinyl-6-one), and have …

WebNov 14, 2000 · Cuprophilicity: Spectroscopic and Structural Evidence for Cu−Cu Bonding Interactions in Luminescent Dinuclear Copper(I) Complexes with Bridging Diphosphane Ligands Chi‐Ming Che Prof. Dr. [email protected] Department of Chemistry, The University of Hong Kong Pokfulam Road, Hong Kong SAR (P.R. China) Fax: (+852) 2857‐1586 WebUsing cuprophilicity as a multi-responsive chromophore switching color in response to temperature, mechanical force and solvent vapors. Journal of Materials Chemistry C 2013, 1 (28) , 4339.

WebJan 10, 2024 · Theoretical calculations break down the attractive and repulsive forces associated with cuprophilicity, its spontaneous 4p-3d hybridization origin, and direction … WebJun 28, 2013 · A stimuli-responsive material with AND logic function was realized by modulating sensitive Cu-Cu interactions, which is quite different from traditional photoinduced electron transfer (PET)...

WebCuprophilicity, a still elusive concept: a theoretical analysis of the ligand-unsupported Cu I –Cu I interaction in two recently reported complexes Josep-M. Poblet and M. Bénard, …

WebThe meaning of COPROPHILIA is marked interest in excrement; especially : the use of feces or filth for sexual excitement. rms webcamsWebJun 7, 2013 · Using cuprophilicity as a multi-responsive chromophore switching color in response to temperature, mechanical force and solvent vapors Request PDF Using cuprophilicity as a... snacks to buy for campingWebMar 25, 2024 · The concept of accomplice liability means an accomplice faces the same degree of guilt and punishment as the individual who committed the crime. Indeed, … rms weather